Assessment of environmental risk of radioactively contaminated industrial tailings

INTAILRISK

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Bosnia &
Herzegovina

Slovenia

Serbia & Montenegro

Croatia

Albania

Russia

Kyrgyzstan

Coal Burning Power Plants (CBPP)
In some regions of Hungary (mainly in the region of Mecsek mountains and on the territory from the Balaton highland to Tatabanya city) the natural radioactivity of the coals is 20-100 times higher than that of the worldwide average. Those mines mostly have been closed, but the ash and slag remained after combustion was deposited in huge tailings ponds.

Coal mining site 238U series 232Th series 40K
Oroszlány 99 24 163
Ajka 120-480 12-35 56-190
Borsod* 38-52 32-62 190-264
Pécs 175 127 560
Várpalota* 220 20 30
Visonta 20 15 80
Komló* 150 97 384
Dorog* 40 36 194
Tata* 100-140 30 162-270
With most of the coal mines closed, the existing CBPP work on imported coals or switched to gas combustion. As a result of coal combustion, around 100 million tons of slag and ash was produced, more of this material is still in the environment.
The highest Th-232 concentration was measured in the ash and slag mixture in the tailings ponds of the Pannonpower Co. near Pecs city (186 Bq.kg-1), and the lowest was in the Ajka power plant ash (19 Bq.kg-1). The U-238 concentration was highest in the Ajka power plant ash, (1459 Bq.kg-1), the lowest was measured in Inota.
The list of present and past operating Hungarian coal fired power plants is presented in Table 2.
Some of the coal fired power plant tailings ponds have been recultivated by covering with a thin (approximately 30 cm) layer of local uncontaminated soil. At some places phytoremediation was done.
Power plant Power (MW)
Bakony Power Co.  
- Ajka Power Plant+ 102
- Inota Power Plant+ 52
Mátra Power Co. 836
Pécs Power Co. (Pannonpower Co) + 190
Borsod Energy Ltd.  
- Borsod Power Plant* 137
- Tiszapalkonya Power Plant* 200
Vértes Power Co.  
- Oroszlány Power Plant 235
- Tatabánya Power Plant 34

Pecs coal fired power plant
During several years of operation of the CBPP near city Pecs in Southern Hungary, 28 million tons of ash and slag, containing elevated levels of naturally occurring radioactive materials (NORM) have been produced. This ash and slag mixture in a water suspension form has been released to the environment into a controlled and monitored area near the plant, surrounded by dams. The wastes formed huge ponds, gradually drying as the water from the ponds has been recovered and recycled.

The area of the tailings ponds comprises approximately 270 hectares. The ash and slag mixture was deposited directly on the soil surface without any pretreatment. The thickness of the deposited material varies between 18 and 21 m. Outskirts of the city Pecs are near the Northern edge of the tailings ponds, and in the South the area borders agricultural lands. The area consists of old dumping areas that have been restored by 30 cm soil layer and vegetated by mixed gramineous plants and trees, and unrestored dried tailings ponds and fresh tailings ponds which are currently in use.
According to the market strategy of the company, coal buring will be terminated in 2004 and the electric power production in the future will be based on gas burning. In view of this long-term strategy and taking into account the demands of the growing urban and industrial areas of the nearby city Pecs the power plant company decided to launch an environmental restoration program, which is in progress now.
The main goals of the planned remediation are: reduction of the contamination of the surrounding territories by resuspension, decreasing the external gamma dose rate and of the radon exhalation from the surface. An important task is to work out recommendations for future industrial, agricultural, and urban utilization. Intensive radiological pre-remediation survey in this area is in progress, the tailings ponds systems could be used as reference test site for remediation.
Ajka coal fired power plant
The coal combustion near city Ajka started in the 30-ies of the last century, and approximately 14 million tons of ash was damped out covering now around 170 hectares. According to the decision of the appropriate authorities coal combustion seems to come to an end in 2004. The tailings ponds will be subject for remediation. At present parts of the ash and slag produced in the Ajka coal fired power plant are used as dam and cover material for the nearby red mud tailings pond. Part of the tailings is located closed to the city. On the tailings ponds water-recycling pools were created, some of them has been already temporarily covered by soil layers.

Aluminium: Neszmely red mud tailings pond

Intensive bauxite mining was going on in Hungary in the 70-80-ies. The average bauxite production was about 2 million tons per year. In the 90-ies most of the bauxite mines have been closed, but as in the case of the coal fired power plants, the wastes are still in the environment. Nowadays the bauxite production is stabilized on the 1 million tons per year level.
In the alumina production industry the Bayer ore processing is used exclusively, producing by a series of processing procedures alumina earth (Al2O3). During the processing of poor quality Hungarian ores a lot of red mud is produced. Production of 1 ton of alumina earth resulted in production of 1.2-1.4 tons of red mud.
The natural radioactivity of Hungarian bauxite ore is in the range of the world average. At some places, however, the radioactivity is 2-3 time higher.

Alumina earth production was terminated everywhere except in Ajka city and Mosonmagyarovar city, the production is 300-400 thousand tons and 100 thousand tons respectively. The tailings ponds contain approximately 20 million tons of red mud on a 200 hectare territory. The ponds are partly recultivated by using soil and ash and slag material from the Ajka CBPP. For the case study the tailings pond of Almasfuzito Alumina Earth Co. near Neszmely village is proposed, as it is completely intact and located very close to the Danube river bed. Around 4 million tons of red mud is deposited in a valley closed by dam, the underlaying soil consists of clay minerals in a large proportion. The external gamma dose-rate varies in a range 200-400 nSv/h at 1 m above the surface of the tailings material. The area is in an intensively cultivated agricultural region, the territory is privatized and remediation is planned in the future.

In bauxite treatment the Bayer process is used in Hungary. By this technology producing 1 ton of aluminium ore appr. 1,2-1,45 tons of red mud is produced. Only the part of the produced aluminium ore was melted in Hungary in plants in Ajka and Inota, the first plant has been shut down. The radioactivity of the Hungarian bauxite is in the range of the worldwide average, only in Csordakút mine was found higher radioactivity ore.

Ac-228 Pa-234m Bi-214 K-40
163-191 203-438 223-263 10-66
Ac-228 Pa-234m Bi-214 K-40
118-447 355-856 238-791 22-82
Most of the radioactivity of the aluminium ore is accumulated in the red mud. Typical radioactivity of the red mud in Hungary is shown in Table 5.
Ac-228 Pa-234m Bi-214 K-40
250-392 369-949 250-568 38-101